Hi Kim,
I love Port Orleans French Quarter! It's a charming resort.
You can reserve the earliest time available for your Crystal Palace character breakfast! Buses begin picking up early diners at 6:30 a.m. from all WDW-owned resorts. You will go to the bus stop and look for a bus marked "Magic Kingdom". Note that early morning buses used to be marked Character Breakfast bus. Now, they only indicate their destination.
As soon as you board the bus, let the bus driver know that you are headed to an early morning breakfast reservation inside the Magic Kingdom.
If you have been waiting longer than 20 minutes with no bus for your destination, feel free to call the Bus Operation Center directly at 407-824-7092. Or visit the Front Desk to make the call for you.
Thanks to
Disney Mom Kay for recently verifying this information during her recent trip to WDW, I'm able to assure you that you'll be able to book an early ADR at Crystal Palace!
Enjoy breakfast with Pooh and friends!